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C1s and O1s gas phase shake-up spectra from Mo(CO)6
Högskolan i Gävle, Institutionen för matematik, natur- och datavetenskap, Ämnesavdelningen för naturvetenskap.
Vise andre og tillknytning
1994 (engelsk)Inngår i: Chemical Physics, ISSN 0301-0104, E-ISSN 1873-4421, Vol. 179, nr 3, s. 303-312Artikkel i tidsskrift (Fagfellevurdert) Published
Abstract [en]

Experimental high-resolution core photoelectron C1s and O1s shake-up spectra of molybdenum hexacarbonyl, Mo(CO)(6), are reported and compared with results of semiempirical INDO/CI calculations. Several hitherto unobserved peaks are identified and assigned. It is found that an intra- and inter-group classification can be used to describe the transitions. The transitions of lowest energy have Mo-CO inter-group character. Dynamical effects on the line widths of the experimental shake-up peaks are discussed. A discussion of the relevance of experimental results obtained for the Mo(CO)(6)e for CO adsorption on metal surfaces is presented.

sted, utgiver, år, opplag, sider
1994. Vol. 179, nr 3, s. 303-312
Identifikatorer
URN: urn:nbn:se:hig:diva-1192DOI: 10.1016/0301-0104(94)87009-8ISI: A1994MV91500005OAI: oai:DiVA.org:hig-1192DiVA, id: diva2:117854
Tilgjengelig fra: 2008-01-15 Laget: 2008-01-15 Sist oppdatert: 2018-03-13bibliografisk kontrollert

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