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Using end-confined chains to model end-absorbing, triblock copolymers: 1. Analytical approach
Physical Chemistry, Royal Institute of Technology, Stockholm, Sweden.
1998 (English)In: Macromolecules, ISSN 0024-9297, E-ISSN 1520-5835, Vol. 31, no 25, 9026-9032 p.Article in journal (Refereed) Published
Abstract [en]

The bridging attraction, mediated by associative, triblock copolymers with insoluble end blocks and a soluble spacer block, is analyzed using scaling arguments and analytical methods. Adsorbing these associative polymers (APs) onto a single surface, the approach of another, bare, surface results in a strong bridging attraction. When both slit surfaces bear adsorbed APs, the bridging attraction is much weaker. The main contribution is an entropic gain since bridge formation decreases the monomer number density in the crowded region near the surface.

Place, publisher, year, edition, pages
1998. Vol. 31, no 25, 9026-9032 p.
Keyword [en]
Adsorption, Mathematical models, Molecular structure, Monomers, Numerical methods, Solubility, Bridging attraction, Mean-field model, Block copolymers
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:hig:diva-25388Scopus ID: 2-s2.0-0032289934OAI: oai:DiVA.org:hig-25388DiVA: diva2:1147999
Available from: 2017-10-09 Created: 2017-10-09 Last updated: 2017-10-09Bibliographically approved

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