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Using end-confined chains to model end-absorbing, triblock copolymers: 2. Numerical approach
Physical Chemistry, Royal Institute of Technology, Stockholm, Sweden.
Physical Chemistry, Royal Institute of Technology, Stockholm, Sweden.
1998 (English)In: Macromolecules, ISSN 0024-9297, E-ISSN 1520-5835, Vol. 31, no 25, 9033-9043 p.Article in journal (Refereed) Published
Abstract [en]

The bridging attraction mediated by end-absorbing, triblock copolymers in a good solvent is analyzed using numerical methods and compared to analytical results. Good agreement is found. The main deviations may be attributed to the neglect of thermal fluctuations in the extension of the loops at the brush edge in the analytical treatment. With a suitable choice of "natural" units, the numerical results for the bridging probability and the free energy of interaction per chain collapse onto universal master curves in the two arrangements considered: symmetric and asymmetric adsorption of associative polymers (APs) on the surfaces of a planar slit.

Place, publisher, year, edition, pages
1998. Vol. 31, no 25, 9033-9043 p.
Keyword [en]
Adsorption, Free energy, Molecular structure, Numerical methods, Solvents, Bridging attraction, Block copolymers
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:hig:diva-25389Scopus ID: 2-s2.0-0032302025OAI: oai:DiVA.org:hig-25389DiVA: diva2:1148014
Available from: 2017-10-09 Created: 2017-10-09 Last updated: 2017-10-09Bibliographically approved

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