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C1s and O1s gas phase shake-up spectra from Mo(CO)6
University of Gävle, Department of Mathematics, Natural and Computer Sciences, Ämnesavdelningen för naturvetenskap.
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1994 (English)In: Chemical Physics, ISSN 0301-0104, E-ISSN 1873-4421, Vol. 179, no 3, p. 303-312Article in journal (Refereed) Published
Abstract [en]

Experimental high-resolution core photoelectron C1s and O1s shake-up spectra of molybdenum hexacarbonyl, Mo(CO)(6), are reported and compared with results of semiempirical INDO/CI calculations. Several hitherto unobserved peaks are identified and assigned. It is found that an intra- and inter-group classification can be used to describe the transitions. The transitions of lowest energy have Mo-CO inter-group character. Dynamical effects on the line widths of the experimental shake-up peaks are discussed. A discussion of the relevance of experimental results obtained for the Mo(CO)(6)e for CO adsorption on metal surfaces is presented.

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1994. Vol. 179, no 3, p. 303-312
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URN: urn:nbn:se:hig:diva-1192DOI: 10.1016/0301-0104(94)87009-8ISI: A1994MV91500005OAI: oai:DiVA.org:hig-1192DiVA, id: diva2:117854
Available from: 2008-01-15 Created: 2008-01-15 Last updated: 2018-03-13Bibliographically approved

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Bustad, Johnny

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