Unsteady flow patterns of interacting buoyant plumes are important for buoyant ventilation and particularly influence pollutant and heat transports in indoor and outdoor environments. This study reveals fundamental large-scale flow patterns in triple building plumes, investigates vortex moving trends during the pattern transition processes, and explores possible mechanisms of pattern diversity by two-dimensional (2-D) Particle Image Velocimetry (PIV). Total five tests are studied, including three different heat strengths Q (180, 90, and 30 W) and three source layouts characterized by the ratios of source spacing S to source width W (0.2, 0.5, and 1.0). Streamline distributions and axial velocity profiles clearly reveal three fundamental global flow patterns: a right-slanting asymmetrical flow pattern, a left-slanting asymmetrical flow pattern, and an axisymmetric flow pattern. Correspondingly, it indicates four basic transition processes, i.e., right-to-center, left-to-center, center-to-right, and center-to-left transitions (“center” represents the axisymmetric pattern). A novel vortex tracking method, based on lambda-2 (λ2) criterion and principles of the PIV technique, is developed and successfully applied to qualitatively track the vortex moving trends during the transition processes. The regular vortex moving trends are found to be reasonably consistent with the global pattern transition trends. The flow pattern diversity is speculated to be mainly driven by unstable heat source wall flows and downstream swaying motions in this study. These critical unstable motions are considered to probably relate to unstable lateral entrainment and vortex interaction, particularly beside the central plume. Consistently, the regular vortex moving trends are usually observed in and around the central plume.