In order to constitute a realistic option to existing travel modes, carpooling needs to be able to offer adequate levels of accessibility. Insights into how carpooling services affect perceived accessibility up until now remain unexplored. In this study we explore carpooling experiences of 122 users in Sweden and examine a number of possible determinants of the perceived accessibility of carpooling. Results show that carpooling is not perceived by the users as particularly accessible with low levels across the sample. Moreover, multiple linear hierarchical regression analyses show that simplicity of travel, population density, years of education, and school and work-trips appear to affect perceptions of accessibility of carpooling, whereas travel time and cost appear not to. The final model explains a third of the variance in perceived accessibility of carpooling, thus nearly two thirds of the variation is still unaccounted for. Future research should explore further possible determinants of perceived accessibility of carpooling in order to explain, understand, and counteract the low levels of accessibility that appear to be linked to this specific travel mode.