The study explores the viability of the PV-Diesel Hybrid system for rural electrification in Sub-Sahara Africa with a study case of a remote district without access to electricity in the Northern Province of Zambia. Using HOMER (Hybrid Optimization of Multiple Electric Renewables) software, the study investigates the best and most feasible technical solution through different hybrid system configurations and combinations, taking into account the least Levelized Cost of Electricity of the project. The results show that operating diesel generators as stand-alone is not economically sustainable and gives a high LCoE due to variability in diesel pump prices, and a high cost of operation and maintenance. Furthermore, the study shows that the initial capital cost of solar energy projects in Zambia is relatively high compared to the equivalent diesel-based plants. However, the authors project that this will likely change because of the continued downward trend in capital costs of PV per kWp. Additionally, the high initial capital costs are offset by the low operational costs and the clean/environmentally friendly energy from PV systems.