Three optional pellet production processes integrated with an existing biomass-based CHP plant using different raw materials (wood chips and solid hydrolysis residues) are studied. The year is divided into 12 periods, and the integrated biorefinery systems are modeled and simulated for each period. The annual economic performance of three integrated biorefinery systems is analyzed based on the simulation results. The option of pellet production integrated with the existing CHP plant with the exhaust flue gas and superheated steam as drying mediums has the lowest specific pellet production cost of 105 €/tpellet, the shortest payback time of less than 2 years and the greatest CO2 reduction of the three options. An advantage in common among the three options is a dramatic increase of the total annual power production and significant CO2 reduction in spite of a small decrease of power efficiency.
The aim of this work was to study the dilute acid pretreatment of rice straw (RS) and fermentable sugar recovery at high solid loadings at pilot scale. A series of pretreatment experiments were performed on RS resulting in >25 wt% solids followed by enzymatic hydrolysis without solid-liquid separation at 20 and 25 wt% using 10 FPU/g of the pretreated residue. The overall sugar recovery including the sugars released in pretreatment and enzymatic hydrolysis was calculated along with a mass balance. Accordingly, the optimized conditions, i.e. 0.35 wt% acid, 162 °C and 10 min were identified. The final glucose and xylose concentrations obtained were 83.3 and 31.9 g/L respectively resulting in total concentration of 115.2 g/L, with a potential to produce >50 g/L of ethanol. This is the first report on pilot scale study on acid pretreatment of RS in a screw feeder horizontal reactor followed by enzymatic hydrolysis at high solid loadings.
Microalgae enable fixation of CO2 into carbohydrates, lipids, and proteins through inter and intracellularly biochemical pathways. These cellular components can be extracted and transformed into renewable energy, chemicals, and materials through biochemical and thermochemical transformation processes. However, recalcitrant cell wall and lack of environmentally benign efficient pretreatment processes are key obstacles in the commercialization of microalgal biorefineries. Thus, current article describes the microalgal chemical structure, type, and structural rigidity and summarizes the traditional pretreatment methods to extract cell wall constituents. Green solvents such as ionic liquid (ILs), deep eutectic solvents (DES), and natural deep eutectic (NDESs) have shown interesting solvent characteristics to pretreat biomass with selective biocomponent extraction from microalgae. Further research is needed in task-specific IL/DES design, cation-anion organization, structural activity understanding of ILs-biocomponents, environmental toxicity, biodegradability, and recyclability for deployment of carbon-neutral technologies. Additionally, coupling the microalgal industry with biorefineries may facilitate waste management, sustainability, and gross revenue.
Consolidated bioprocessing (CBP) is characterized by a single-step production of value-added compounds directly from biomass in a single vessel. This strategy has the capacity to revolutionize the whole biorefinery concept as it can significantly reduce the infrastructure input and use of chemicals for various processing steps which can make it economically and environmentally benign. Although the proof of concept has been firmly established in the past, commercialization has been limited due to the low conversion efficiency of the technology. Either a native single microbe, genetically modified microbe or a consortium can be employed. The major challenge in developing a cost-effective and feasible CBP process is the recognition of bifunctional catalysts combining the capability to use the substrates and transform them into value-added products with high efficiency. This article presents an in-depth analysis of the current developments in CBP around the globe and the possibilities of advancements in the future.
There is an immediate global requirement for an ingenious strategy for food waste conversion to biofuels in order to replace fossil fuels with renewable resources. Food waste conversion to bioethanol could lead to a sustainable process having the dual advantage of resolving the issue of food waste disposal as well as meeting the energy requirements of the increasing population. Food waste is increasing at the rate of 1.3 billion tonnes per year, considered to be one-third of global food production. According to LCA studies discarding these wastes is detritus to the environment, therefore; it is beneficial to convert the food waste into bioethanol. The CO2 emission in this process offers zero impact on the environment as it is biogenic. Among several pretreatment strategies, hydrothermal pretreatment could be a better approach for pretreating food waste because it solubilizes organic solids, resulting in an increased recovery of fermentable sugars to produce bioenergy.
The aim of this study is to find potential utilization practice of rice straw in India from an environmental perspective. Life cycle assessment (LCA) is conducted for four most realistic utilization practices of straw including: (1) incorporation into the field as fertilizer (2) animal fodder (3) electricity (4) biogas. The results show that processing of 1 ton straw to electricity and biogas resulted in net reduction of 1471 and 1023 kg CO2eq., 15.0 and 3.4 kg SO2eq. and 6.7 and 7.1 kg C2H6eq. emissions in global warming, acidification and photochemical oxidation creation potential respectively. Electricity production from straw replaces the coal based electricity and resulted in benefits in most of the environmental impacts whereas use as an animal fodder resulted in eutrophication benefits. The burning of straw is a harmful practice of managing straw in India which can be avoided by utilizing straw for bioenergy.
In this paper, the configuration and performance of a polygeneration system are studied by modelling the integration of a lignocellulosic wood-to-ethanol process with an existing combined heat and power (CHP) plant. Data from actual plants are applied to validate the simulation models. The integrated polygeneration system reaches a total efficiency of 50%, meeting the heating load in the district heating system. Excess heat from the ethanol production plant supplies 7.9 MW to the district heating system, accounting for 17.5% of the heat supply at full heating load. The simulation results show that the production of ethanol from woody biomass is more efficient when integrated with a CHP plant compared to a stand-alone production plant. The total biomass consumption is reduced by 13.9% while producing the same amounts of heat, electricity and ethanol fuel as in the stand-alone configurations. The results showed that another feature of the integrated polygeneration system is the longer annual operating period compared to existing cogeneration. Thus, the renewable electricity production is increased by 2.7% per year.