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  • 1.
    Wang, Zhao
    et al.
    KTH, Kemisk apparatteknik.
    Liu, Longcheng
    KTH, Kemisk apparatteknik.
    The swelling pressure of Na-bentonite: Study with a density functional approach2012In: Chemistry Letters, ISSN 0366-7022, E-ISSN 1348-0715, Vol. 41, no 10, p. 1346-1348Article in journal (Refereed)
    Abstract [en]

    The combination of the fundamental measure theory (FMT) and the weighted correlation approach (WCA) within the framework of the density functional theory, i.e., the FMT/ WCA approach, is applied to study the swelling pressure of Nabentonite at different salt conditions. Good agreement between the FMT/WCA simulations and the results from both experiments and a Donnan-equilibrium-based DLVO model suggests that the hydration repulsion between charged surfaces can be well accounted by the ionion correlations effect.

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