This study adapted the mean age of air, a time scale widely utilized in evaluating indoor ventilation, to assess the impact of building layouts on urban ventilation capacity. To distinguish it from its applications in enclosed indoor environments, the adapted index was termed the effective mean age of air (T_E). Based on an experimentally validated method, computational fluid dynamic (CFD) simulations were performed for parametric studies on four generic parameters that describe urban morphologies, including building height, building density, and variations in the heights or frontal areas of adjacent buildings. At the breathing level (z = 1.7 m), the results indicated three distinct distribution patterns of insufficiently ventilated areas: within recirculation zones behind buildings, in the downstream sections of the main road, or within recirculation zones near lateral facades. The spatial heterogeneity of ventilation capacity was emphasized through the statistical distributions of T_E. In most cases, convective transport dominates the purging process for the whole canopy zone, while turbulent transport prevails for the pedestrian zone. Additionally, comparisons with a reference case simulating an open area highlighted the dual effects of buildings on urban ventilation, notably through the enhanced dilution promoted by the helical flows between buildings. This study also serves as a preliminary CFD practice utilizing T_E with the homogenous emission method, and demonstrates its capability for assessing urban ventilation potential in urban planning.